Our goal is to learn about the political interests and preferences of the Members of Parliament by mining their parliamentary activity, in order to develop a recommendation/filtering system that, given a stream of documents to be distributed among them, is able to decide which documents should receive each Member of Parliament. We propose to use positive unlabeled learning to tackle this problem, because we only have information about relevant documents (the own interventions of each Member of Parliament in the debates) but not about irrelevant documents, so that we cannot use standard binary classifiers trained with positive and negative examples. We have also developed a new algorithm of this type, which compares favourably with: a) the baseline approach assuming that all the interventions of other Members of Parliament are irrelevant, b) another well-known positive unlabeled learning method and c) an approach based on information retrieval methods that matches documents and legislators' representations. The experiments have been carried out with data from the regional Andalusian Parliament at Spain.