LiDAR sensors are essential for autonomous systems, yet LiDAR fiducial markers (LFMs) lag behind visual fiducial markers (VFMs) in adoption and utility. Bridging this gap is vital for robotics and computer vision but challenging due to the sparse, unstructured nature of 3D LiDAR data and 2D-focused fiducial marker designs. This dissertation proposes a novel framework for mapping and localization using LFMs is proposed to benefit a variety of real-world applications, including the collection of 3D assets and training data for point cloud registration, 3D map merging, Augmented Reality (AR), and many more. First, an Intensity Image-based LiDAR Fiducial Marker (IFM) system is introduced, using thin, letter-sized markers compatible with VFMs. A detection method locates 3D fiducials from intensity images, enabling LiDAR pose estimation. Second, an enhanced algorithm extends detection to 3D maps, increasing marker range and facilitating tasks like 3D map merging. This method leverages both intensity and geometry, overcoming limitations of geometry-only detection approaches. Third, a new LFM-based mapping and localization method registers unordered, low-overlap point clouds. It employs adaptive threshold detection and a two-level graph framework to solve a maximum a-posteriori (MAP) problem, optimizing point cloud and marker poses. Additionally, the Livox-3DMatch dataset is introduced, improving learning-based multiview point cloud registration methods. Extensive experiments with various LiDAR models in diverse indoor and outdoor scenes demonstrate the effectiveness and superiority of the proposed framework.