With the characteristics of vertical take-off and landing and long endurance, tiltrotor has attracted considerable attention in recent decades for its potential applications in civil and scientific research. However, the problems of strong couplings, nonlinear characteristics and mismatched disturbances inevitably exist in the tiltrotor, which bring great challenges to the controller design in transition mode. In this paper, we combined a super-twisting extended state observer (STESO) with an adaptive recursive sliding mode control (ARSMC) together to design a tiltrotor aircraft attitude system controller in transition mode using STESO-ARSMC (SAC). Firstly, the six degrees of freedom (DOF) nonlinear mathematical model of tiltrotor is established. Secondly, the states and disturbances are estimated by the STES observer. Thirdly, ARSM controller is designed to achieve finite time convergence. The Lyapunov function is used to testify the convergence of the tiltrotor UAV system. The new aspect is that the assessments of the states are incorporated into the control rules to adjust for disruptions. When compared to prior techniques, the control system proposed in this work can considerably enhance anti-disturbance performance. Finally, simulation tests are used to demonstrate the efficacy of the suggested technique.